研究

研究室

講師:伊藤 元気(イトウ モトキ)

研究室

機能分子化学

最終学歴

大阪大学大学院薬学研究科博士後期課程(2011年3月)

学位

博士(薬学)(大阪大学:2011年)

講義科目

錯体化学、薬の科学実習Ⅲ-2

専門分野

有機化学

所属学会

日本薬学会、有機合成化学協会

受賞歴

2017年 有機合成化学協会 富士フィルム研究企画賞

研究業績1

One-pot generation of benzynes from 2-aminophenylboronates via a Rh(II)-catalyzed N–H amination/oxidation/elimination cascade process
Ito, M.;Tanaka, A.; Hatakeyama, K.; Kano, E.; Higuchi, K.; Sugiyama, S.
Org. Chem. Front. 2020, 7, 64-68. DOI: 10.1039/C9QO01115C.

研究業績2

Dirhodium(II)-Catalyzed ortho C−H Amination of Sterically Congested N,N-Dialkylanilines Motoki Ito, Tomoya Nakagawa, Kazuhiro Higuchi, Shigeo Sugiyama Org. Biomol. Chem. 2018, 16, 6876-6881. DOI: 10.1039/C8OB01974F.

研究業績3

Rhodium(II)-Catalyzed Synthesis of N-Aryl-N′-tosyldiazenes from Primary Aromatic Amines Using (Tosylimino)aryliodinane: A Potent Stable Surrogate for Diazonium Salts Motoki Ito, Arisa Tanaka, Kazuhiro Higuchi, Shigeo Sugiyama Eur. J. Org. Chem. 2017, 1272-1276. DOI: 10.1002/ejoc.201601627.

研究業績4

Diastereo- and enantioselective intramolecular 1,6-C-H insertion reactions of α-diazo esters catalyzed by chiral dirhodium(II) carboxylates Motoki Ito, Yuji Kondo, Hisanori Nambu, Masahiro Anada, Koji Takeda, Shunichi Hashimoto Tetrahedron Lett. 2015, 56, 1397-1400.

研究業績5

Organocatalytic C-H/C-H' Cross-Biaryl Coupling: C-Selective Arylation of Sulfonanilides with Aromatic Hydrocarbons Motoki Ito, Hiroko Kubo, Itsuki Itani, Koji Morimoto, Toshifumi Dohi, Yasuyuki Kita J. Am. Chem. Soc. 2013, 135, 14078-14081.

研究業績6

Metal-Free C-H Cross-Coupling toward Oxygenated Naphthalene-Benzene Linked Biaryls Toshifumi Dohi, Motoki Ito, Itsuki Itani, Nobutaka Yamaoka, Koji Morimoto, Hiromichi Fujioka, Yasuyuki Kita Org. Lett. 2011, 13, 6208-6211.

研究業績7

Dirhodium(II)-Catalyzed Synthesis of N-(Arylsulfonyl)hydrazines by N–H Amination of Aliphatic Amines

Motoki Ito, Yui Hasegawa, Satomi Saito, Asami Onda, Kazuhiro Higuchi, Shigeo Sugiyama

Synlett 2022, 33, 367-370. DOI: 10.1055/s-0041-1737759.

研究業績8

Silica gel-induced aryne generation from o-triazenylarylboronic acids as stable solid precursors

Motoki Ito, Yuka Yamabayashi, Mio Oikawa, Emi Kano, Kazuhiro Higuchi, Shigeo Sugiyama

Org. Chem. Front. 2021, 8, 2963-2969. DOI: 10.1039/D1QO00385B.

研究業績9

Dirhodium(II)-Catalyzed ortho C–H Amination of N-Alkyldiarylamines

Motoki Ito, Mamiko Mori, Tomoya Nakagawa, Miki Hori, Kazuhiro Higuchi, Shigeo Sugiyama

Heterocycles 2021, 103, 403-415. DOI: 10.3987/COM-20-S(K)27.