研究

研究室

講師:林 賢(ハヤシ サトシ)

研究室

薬品物理化学

最終学歴

東京大学大学院理学系研究科化学専攻博士課程(2006年3月)

学位

博士(理学) (東京大学:2006年)

講義科目

物理化学Ⅱ、薬の発明・発見、錯体化学

専門分野

物理化学、有機化学

研究課題

機能性分子の開発とその評価

所属学会

日本薬学会、日本化学会、有機合成化学協会、日本分光学会

学会活動

次世代を担う有機化学シンポジウム世話人

学内委員

学生実習委員、薬品管理システム運営委員、マルチメディア教育委員会、情報教育センター運営委員会

研究業績1

Heat capacity and glass transition of an ionic liquid 1-butyl-3-methylimidazolium chloride Chem. Phys. Lett., 2006, 423, 371-375.

研究業績2

Magnetic manipulation of materials in a magnetic ionic liquid Appl. Phys. Lett., 2006, 89, 132506.

研究業績3

Raman spectra indicative of unusual water structure in crystals formed from a room-temperature ionic liquid J. Raman Spectrosc., 2006, 37, 1242-1243.

研究業績4

Proton-Conducting Properties of a Bronsted Acid-Base Ionic Liquid and Ionic Melts Consisting of Bis(trifluoromethanesulfonyl)imide and Benzimidazole for Fuel Cell Electrolytes J. Phys. Chem. C, 2007, 111, 1541-1548.

研究業績5

Melting and Freezing Behaviors of Prototype Ionic Liquids, 1-Butyl-3-methylimidazolium Bromide and Its Chloride, Studied by Using a Nano-Watt Differential Scanning Calorimeter J. Phys. Chem. B, 2007, 111, 4894-4900.

研究業績6

An Efficient One-Pot Protocol for Asymmetric Bifunctionalization of 5,15-Disubstituted Porphyrins: Direct Access to meso Activated Alkenyl-Substituted meso-Formylporphyrins Tetrahedron Lett., 2011, 52, 5345-5348.

研究業績7

Palladium-catalyzed Kumada Coupling Reaction of Bromoporphyrins with Silylmethyl Grignard Reagents: Preparation of Silylmethylsubstituted Porphyrins as a Multipurpose Synthon for Fabrication of Porphyrin Systems J. Org. Chem., 2012, 77, 10488-10497.

研究業績8

Palladium-Catalyzed Polyfluorophenylation of Porphyrins with Bis(polyfluorophenyl)zinc Reagents Catalysts, 2013, 3, 839-852.

研究業績9

Bis(zinc Porphyrin) as a CD-Sensitive Bidentate Host Molecule: Direct Determination of Absolute Configuration of Mono-Alcohols Chem. Commun., 2015, 51, 11068-11071.

研究業績10

Regioselective β-silylation of porphyrins via iridium-catalyzed C–H bond activation Org. Biomol. Chem., 2016, 14, 10189-10192.

研究業績11

Preparation of meso-silylporphyrins via nickel-catalyzed coupling of meso-brominated Ni(II) porphyrins with silylzinc reagents Heterocycles, 2018, 97, 1082-1098.

研究業績12

Chiroptical Protocol for the Absolute Configurational Assignment of Alkyl-Substituted Epoxides Using Bis(zinc porphyrin) as a CDSensitive Bidentate Host J. Org. Chem. 2019, 84, 645−652.

研究業績13

Direct determination of the absolute configurations of chiral cyanohydrins using bis(zinc porphyrin) as a CD-sensitive bidentate host Heterocyclcles, 2019, 98, 1215-1227.

研究業績14

Central zinc metal-controlled regioselective meso-bromination of zincated β-silylporphyrins–rapid access to meso,β-dual-functionalized porphyrins Org. Biomol. Chem., 2020, 18, 9791-9795.

研究業績15

Copper-Mediated Trifluoromethylation of Borylporphyrins Using an in situ-Generated CF3 Radical from NaSO2CF3 and tert-Butyl Hydroperoxide Heterocyclcles, 2021, 103, 348-364.